Oxidative β-Cleavage of Fused Cyclobutanols Leading to Hydrofuran-Fused Polycyclic Aromatic Compounds
نویسندگان
چکیده
Treatment of aryl-fused bicyclo[4.2.0]octanols with an oxidant such as phenyliodine diacetate (PIDA) or hypochlorous acid gave dihydrofuran-containing polycyclic aromatic compounds by selective β-cleavage the cyclobutanol moiety. Mechanistic studies suggest that oxygen atom hydrofuran ring is incorporated from hydroxy group substrate via intramolecular addition. The oxidative transformation should serve a new method to prepare functionalized compounds.
منابع مشابه
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ژورنال
عنوان ژورنال: Journal of Organic Chemistry
سال: 2021
ISSN: ['1520-6904', '0022-3263']
DOI: https://doi.org/10.1021/acs.joc.1c01108